If you want to increase the efficiency of your boiler simply turn down the temperature of the system.
Note this is different to turning down the temperature for your rooms or your hot water.
If your boiler is heating your house running at 80C it will not be able to condense and so the efficiency will be 60-75%.
If you turn down the system temperature to say 50C, the boiler will be able to get most of the heat energy from condensing and efficiency could be 80-95%.
Note this does not make your house colder, it still heats the house up to the same temperature, the only difference is that it will take longer to heat your house at 50C than it will at 80C, but just turn your boiler on earlier (and longer) and your good.
Free money.