Should the header tank get warm? And is this causing my condensation?
No, it should not get warm and may well be helping to cause condensation.
This is correct.
The usual suspect is either the open safety vent pipe or the feed & expansion pipe position in relation to the circulating pump. When the system is on, is there water coming out of the osvp. This is the hockey stick shaped open ended pipe curved over the top of the f & e tank. If so, the system is pitching & the tank is acting like a radiator. This will eventually destroy your system.
If not, then the pump is probably pumping into the tank through the f & e pipe. It should be located on the negative side of the pump.
If you do have or wish to have solid fuel with a back boiler, then you could eliminate the f & e tank altogether & pressurise the heating system. You will have a far more efficient heating system with far less issues overall. You will have to of course, install a few more components to do so.
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