we just got insulated slab board (82.5mm) put up on one external wall in a room in our house. Its not yet plastered but the effect is amazing, i have one of them room temp from SEAI, you can order them free of charge for a couple of them. Also when we did the attic (Bungalow) the effect was equally amazing.
Iv a few posts on insulation up here as do others that are well worth a read. Have you draftproofed the attic hatch and other air leakage spots. Iv just done the downlighters for instance although they still need more attention.
We have reservations on pumping walls as heard/seen horror stories of companies not doing good job, mould growth, effect not noticeable, neighbours company went out of business three weeks after they did job!. (others here will disagree with me immediately). However there also seems to be/could be issues with internal insulation but we decided to chance as only one wall.