look at the hot water cylinder, on one side you will see two pipes entering the cylinder about 18" apart and parallel, you should (but may not) see a valve on the bottom pipe, leave that alone. turn off any other valves connected on those line's of pipe and see what happens. if those parallel pipes get hot and the rads stay cool, then you've got it. Also have a look for a valve connected to pipe with a white/red/silver box on it, this is a motorised valve and will be controlled by a swicth. it the house is any way new, it should have these.