Yes the thread, referenced by Leo is very useful. Personally I would go with a wider cavity but I suppose it's too late for you now that the foundations are in?
If you cannot change the cavity width, then how about using an AAC block (e.g. QuinnLite) for the inner leaf. Also I would go ahead with the rigid Kingspan board but would also pump with beads. That would give you 3 layers of insulation compared with the one layer you are looking at at the moment. There's a tool on the sei.ie website that will allow you to calculate the u value of such a wall.
By dry lining you can add a 4th layer but the cost may not be worth it, anyway that's something to consider later anyway.