Legally speaking, the top-up mortgage is a totally separate transaction to the purchase and mortgage of the investment property, so your solicitor is quite correct to charadcerise this as extra work.
The €540 fee (not clear if this is inclusive or exclusive of V.A.T.) does not seem excessive, but as the top-up is a separate transaction, you should feel perfectly free to shop around to see if you can get better value. Frankly, I doubt if you will get it an awful lot cheaper, because your solicitor is in a better position to handle this (being already familiar with this title) than a new solicitor.