Why on earth would they want to complicate things with a savings account like this?
If they are living together and have joint expenses, they can open a joint current account to pay their expenses.
We will call your colleague John.
We will call his girlfriend Mary
We will call her ex, X.
Mary will have to declare her assets in any legal separation or divorce. There may well be an investigation into the source of them. Were they Mary's or John's. Was she just trying to put her assets into John's name?
If John dies, the joint account will become Mary's.
If Mary dies, the joint account will become John's.
But she can probably achieve this by getting legally separated and doing a will.
There is no harm in getting informal views and ideas here, but she should consult her solicitor before opening any account with John.
Brendan