If it just start weeping you may have a perforation on a weld at the vent and need a plumber.
If you vented the radiator prior to the weeping the key may be a little worn
Try a new or different key.
I would isolate the radiator at both ends and Try new vent screw or replace the vent fitting if of appropriate type. or as a strictly temp measure apply a little Fernox LSX when dry.(check system pressure)
You dont mean drain cock by any chance?