First would be to check the usual suspects. Safety valve discharging, automatic air vents weeping, radiator valve glands weeping, low pressure or split expansion vessel diaphragm.
If that does not show up anything, I usually have the system as hot as possible, then use thermal image camera to try & source the leak. This can prove very precise but only sometimes. It really depends on where the leak is.
If that does not work, then the system should be isolated into sectors & pressure tested with compressed air. This does not have to be done at high pressure, it is just to determine the section of pipework that the leak exists in, narrowing down the area. I would also use snake head camera to search under floor boards but not having to lift them/or sections of flooring.