Sorry not sure what you mean - hear the rad or hear the pump?When the stove pump is running, can you hear it?
Is the oil boiler close to problem rad?
When I say hear, i mean the pump. By and large, if the pump is making noise it is either pumping water with air in it or on the way out.
As already suggested, when back boiler is on, turn off a few rads that heat to see if problem rad heats.
You have a complex enough case, you put in a stronger pump and it may cause pitching (Water being pumped into small tank in attic). Dual systems can be a pain when there are problems.
Hard to advise without seeing how your system is set up.
2. Close all rads except one. Repeat with a different one open. During this, you may hear air getting pushed into the open radiator.
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