When it comes to inheiritance tax, you will fall into Category C which has a tax free exemption of of 16,700 euros. That is the first 16,700 is tax free. Every thing above that you pay CAT tax at a rate of 20%.
If you were inheiriting directly from your uncle, you would fall into Category B which has a tax free exemption of 33,500 euros. You are not. You are inheriting from his wife. To the best of my knowledge, Revenue does not give a you an additional exemption based on you having a blood relationship with the person who was the original source of the inheiritance.