In no way is the Sigma a special or unique boiler, it was chosen to be used in this fashion as it has a cast iron heat exchanger (as do a fair few others, ideal classic, Baxi solo etc)
and still should not be used on a mixed water system, the only reason they are chosen by an installer is the fact that the cast iron heat exchanger acts as a heat sink meaning the boiler is less likely to trip on its hi limit stat when subjected to excessive heat from a back boiler. This boiler would not be classed as a hi eff boiler (most likely class d)
and should have not cost any extra!