You can request a charge back on a Visa Debit Card.
In terms of paying off a holiday, you would need to lodge to your account and then make a payment with the card. You can only spend your available balance on your current account.
I had to go down the road of a chargeback on a visa debit card through Halifax (when they were in IRL). One of their droids did the best he could to tell me that I didn't have the same protection as a visa CC. Long protracted drawn out process involving visa europe and then Halifaxes fraud dept. (again they were doing their best to palm me off) but ultimately, they paid out. So if you ever have your bank suggest this in the even of needing a chargeback, don't take their word for it!