The fact that she is an OAP is irrelevant.
She may be able to claim principal private residence relief - but this will depend on a number of factors, including was the garage attached to the house. Did it represent part of the house/property? If so, no tax may be due.
If it's completely separate it's unlikely that PPR can be claimed and tax will may due on the profits.
To calculate the gain you need to work out what it cost to purchase. If you don't know an auctioneer will be able to get you a valuation. It's important to note that if it was purchased/acquired pre 1974 - you should get a valuation at April 1974 and this will be your base cost.
Finally, I would advise getting some professional advice on this matter before proceeding as the above is a quick summary.
Best of luck