CAT is calculated on the value of an inheritance.
Everyone has a tax-free threshold of € 335,000 (February 2024 value) - it is now € 400,000 but as your father died in February 2024, this is the value to be used.
The calculation is base don the cumulative value of inheritances and gifts received from parents since Dec 1991
The value can be reduced by the dwelling house relief but as the total value is below the threshold, this is not relevant.
No tax would be due if your brother inherits the whole house as its value is below the threshold.
You don't say if there was a will - if not, then your father's estate would be divided amongst all his children equally