I'd check the boiler internal's in around the combustion chamber/heat exchanger. What type of boiler is it? How old is the boiler? Have you noticed water dripping from under the boiler before. If you have water dripping from under the boiler. Is this actually through the boiler base cover? If so you have a leak in the boiler. Possible a leaking heat exchanger?
Just replaced a leaking heat exchanger in a Mynute 14SE boiler, Boiler was 6 years old. Wasn't until I opened the front cover, that I observed a pool of water. A pin hole leak in the heat exchanger was the cause. It damaged the insulation on the combustion. Repalced the heat exchanger and combustion chamber and all okay again.